Structure
Noun + である
[な]Adjective + である
Details
Formal
About である
である (or であります) is a construction in Japanese that is considered to be the formal equivalent of だ. This should not be confused with the polite speech word です, as である is simply a combination of the conjunctive form of だ, and the う - Verb, ある.
である may be used in any place that だ would usually be used, but is most likely to be found at the end of sentences/statements.
Fun Fact
Because the な that is used with な-Adjectives is simply the attributive form of だ, である may replace な or の when connecting one noun to another. The attributive form just means the form of a word that can be directly linked to a noun. As ある's attributive form is just ある, it does not need to be modified at all.
However, although this is grammatically correct, it would sound quite stiff in many circumstances, and should be avoided in standard speech.
Caution
であります (as opposed to である) is very formal, and will almost exclusively be used by people within jobs that absolutely require this level of formality (politics, police force, military, etc). Due to this, its use within regular conversation will sound stiff, or perhaps even like the speaker is jokingly being over polite.
Synonyms
Related
Vocab Coverage
All Bunpro Vocab that appears on this item.
Examples
--:--
彼はとてもハンサムである。
He is very handsome.
彼はパイロットであった。
He was a pilot.
とても面白いドラマである。
It is a very interesting drama.
題名:「吾輩は猫である。」
Title: 'I am a cat.'
夢は海外で成功することである。
My dream is to be successful overseas.
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Formal expressions
Tae Kim
Japanese Literary Style
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Tae Kim's Japanese Grammar Guide
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である – Grammar Discussion
Most Recent Replies (15 in total)

JamesBunpro
You raise a good point. (I am going to answer this in a slightly technical way, but it is worth noting for any N3 users reading this thread that the information below is absolutely not needed to understand the grammar point.)
The reason we use this analysis is as you mention (usage based). Besides this, there are practical reasons to analyse である as the 連用形 of だ plus ある.
Firstly, in Japanese school grammar, this breakdown is standard. One reason being that if we want to have a tidy conjugation chart with 未然形、連用形、終止形、連体形、仮定形、命令形 then で slots in nicely. Refer to this and this to see a standard example of how this is handled in school grammar.

oppy
There’s a typo in the Fun Fact section: ‘modifed’

JamesBunpro
Fixed!
Good catch - thank you